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HFC-152a and HFC-134a emission estimates and characterization of CFCs, CFC replacements, and other halogenated solvents measured during the 2008 ARCTAS campaign (CARB phase) over the South Coast Air Basin of California
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Barletta B.; Nissenson P.; Meinardi S.; et al. - Copernicus GmbH, 2011This work presents results from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) study. Whole air samples were obtained on board research flights that flew over California during June 2008 and analyzed for selected volatile organic compounds, including several halogenated species. Samples collected over the South Coast Air Basin of California (SoCAB), which includes much of Los Angeles (LA) County, were compared with samples from inflow air masses over the Pacific Ocean. The levels of many halocarbon species were enhanced significantly over t ...
[article]HFC-152a and HFC-134a emission estimates and characterization of CFCs, CFC replacements, and other halogenated solvents measured during the 2008 ARCTAS campaign (CARB phase) over the South Coast Air Basin of California
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Available online: http://dx.doi.org/10.5194/acp-11-2655-2011
B. Barletta ; P. Nissenson ; S. Meinardi ; D. Dabdub ; F. Sherwood Rowland ; R.A. VanCuren ; J. Pederson ; G.S. Diskin ; D.R. Blake
in Atmospheric Chemistry and Physics (ACP) > Vol. 11. N° 3 [03/01/2011] . - p.2655-2669This work presents results from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) study. Whole air samples were obtained on board research flights that flew over California during June 2008 and analyzed for selected volatile organic compounds, including several halogenated species. Samples collected over the South Coast Air Basin of California (SoCAB), which includes much of Los Angeles (LA) County, were compared with samples from inflow air masses over the Pacific Ocean. The levels of many halocarbon species were enhanced significantly over the SoCAB, including compounds regulated by the Montreal Protocol and subsequent amendments. Emissions estimates of HFC-152a (1,1-difluoroethane, CH3CHF2; 0.82 ± 0.11 Gg) and HFC-134a (1,1,1,2-tetrafluoroethane, CH2FCF3; 1.16 ± 0.22 Gg) in LA County for 2008 were obtained using the observed HFC:carbon monoxide (CO) enhancement ratio. Emission rates also were calculated for the SoCAB (1.60 ± 0.22 Gg yr−1 for HFC-152a and 2.12 ± 0.28 Gg yr−1 for HFC-134a) and then extrapolated to the United States (32 ± 4 Gg yr−1 for HFC-152a and 43 ± 6 Gg yr−1 for HFC-134a) using population data. In addition, emission rates of the two HFCs in LA County and SoCAB were calculated by a second method that utilizes air quality modeling. Emissions estimates obtained using both methods differ by less than 25% for the LA County and less than 45% for the SoCAB.
Language(s): English
Format: Digital (Free)Tags: Aerosols ; Atmosphere ; Air pollution ; United States of America
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Mesoscale convective systems observed during AMMA and their impact on the NOx and O3 budget over West Africa
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Huntrieser H.; Schlager H.; Lichtenstern M.; et al. - Copernicus GmbH, 2011During the "African Monsoon Multidisciplinary Analysis" (AMMA) field phase in August 2006, a variety of measurements focusing on deep convection were performed over West Africa. The German research aircraft Falcon based in Ouagadougou (Burkina Faso) investigated the chemical composition in the outflow of large mesoscale convective systems (MCS). Here we analyse two different types of MCS originating north and south of the intertropical convergence zone (ITCZ, ~10° N), respectively. In addition to the airborne trace gas measurements, stroke measurements from the Lightning Location Network (LINE ...
[article]Mesoscale convective systems observed during AMMA and their impact on the NOx and O3 budget over West Africa
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Available online: http://dx.doi.org/10.5194/acp-11-2503-2011
H. Huntrieser ; H. Schlager ; M. Lichtenstern ; P. Stock ; T. Hamburger ; H. Höller ; K. Schmidt ; H.-D. Betz ; A. Ulanovsky ; F. Ravegnani
in Atmospheric Chemistry and Physics (ACP) > Vol. 11. N° 3 [03/01/2011] . - p.2503-2536During the "African Monsoon Multidisciplinary Analysis" (AMMA) field phase in August 2006, a variety of measurements focusing on deep convection were performed over West Africa. The German research aircraft Falcon based in Ouagadougou (Burkina Faso) investigated the chemical composition in the outflow of large mesoscale convective systems (MCS). Here we analyse two different types of MCS originating north and south of the intertropical convergence zone (ITCZ, ~10° N), respectively. In addition to the airborne trace gas measurements, stroke measurements from the Lightning Location Network (LINET), set up in Northern Benin, are analysed. The main focus of the present study is (1) to analyse the trace gas composition (CO, O3, NO, NOx, NOy, and HCHO) in the convective outflow as a function of distance from the convective core, (2) to investigate how different trace gas compositions in the boundary layer (BL) and ambient air may influence the O3 concentration in the convective outflow, and (3) to estimate the rate of lightning-produced nitrogen oxides per flash in selected thunderstorms and compare it to our previous results for the tropics. The MCS outflow was probed at different altitudes (~10–12 km) and distances from the convective core (<500 km). Trace gas signatures similar to the conditions in the MCS inflow region were observed in the outflow close to the convective core, due to efficient vertical transport. In the fresh MCS outflow, low O3 mixing ratios in the range of 35–40 nmol mol−1 were observed. Further downwind, O3 mixing ratios in the outflow rapidly increased with distance, due to mixing with the ambient O3-rich air. After 2–3 h, O3 mixing ratios in the range of ~65 nmol mol−1 were observed in the aged outflow. Within the fresh MCS outflow, mean NOx (=NO+NO2) mixing ratios were in the range of ~0.3–0.4 nmol mol−1 (peaks ~1 nmol mol−1) and only slightly enhanced compared to the background. Both lightning-produced NOx (LNOx) and NOx transported upward from the BL contributed about equally to this enhancement. On the basis of Falcon measurements, the mass flux of LNOx in the investigated MCS was estimated to be ~100 g(N) s−1. The average stroke rate of the probed thunderstorms was 0.04–0.07 strokes s−1 (here only strokes with peak currents ≥10 kA contributing to LNOx were considered). The LNOx mass flux and the stroke rate were combined to estimate the LNOx production rate. For a better comparison with other published results, LNOx estimates per LINET stroke were scaled to Lightning Imaging Sensor (LIS) flashes. The LNOx production rate per LIS flash was estimated to 1.0 and 2.5 kg(N) for the MCS located south and north of the ITCZ, respectively. If we assume, that these different types of MCS are typical thunderstorms occurring globally (LIS flash rate ~44 s−1), the annual global LNOx production rate was estimated to be ~1.4 and 3.5 Tg(N) a−1.
Language(s): English
Format: Digital (Free)Tags: Region I - Africa ; West Africa ; Atmosphere ; Atmospheric circulation ; Monsoon
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Carbon dioxide atmospheric vertical profiles retrieved from space observation using ACE-FTS solar occultation instrument
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Foucher P.Y.; Chédin A.; Armante R.; et al. - Copernicus GmbH, 2011Major limitations of our present knowledge of the global distribution of CO2 in the atmosphere are the uncertainty in atmospheric transport and the sparseness of in situ concentration measurements. Limb viewing spaceborne sounders such as the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) offer a vertical resolution of a few kilometres for profiles, which is much better than currently flying or planned nadir sounding instruments can achieve. After having demonstrated the feasibility of obtaining CO2 vertical profiles in the 5–25 km altitude range with an accuracy of ...
[article]Carbon dioxide atmospheric vertical profiles retrieved from space observation using ACE-FTS solar occultation instrument
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Available online: http://dx.doi.org/10.5194/acp-11-2455-2011
P.Y. Foucher ; A. Chédin ; R. Armante ; C. Boone ; C. Crevoisier ; P. Bernath
in Atmospheric Chemistry and Physics (ACP) > Vol. 11. N° 3 [03/01/2011] . - p.2455-2470Major limitations of our present knowledge of the global distribution of CO2 in the atmosphere are the uncertainty in atmospheric transport and the sparseness of in situ concentration measurements. Limb viewing spaceborne sounders such as the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) offer a vertical resolution of a few kilometres for profiles, which is much better than currently flying or planned nadir sounding instruments can achieve. After having demonstrated the feasibility of obtaining CO2 vertical profiles in the 5–25 km altitude range with an accuracy of about 2 ppm in a previous study, we present here the results of five years of ACE-FTS observations in terms of monthly mean profiles of CO2 averaged over 10° latitude bands for northern mid-latitudes. These results are compared with in-situ aircraft measurements and with simulations from two different air transport models. Key features of the measured altitude distribution of CO2 are shown to be accurately reproduced by the ACE-FTS retrievals: variation in altitude of the seasonal cycle amplitude and extrema, seasonal change of the vertical gradient, and mean growth rate. We show that small but significant differences from model simulations could result from an over estimation of the model circulation strength during the northern hemisphere spring. Coupled with column measurements from a nadir viewing instrument, it is expected that occultation measurements will bring useful constraints to the surface carbon flux determination.
Language(s): English
Format: Digital (Free)Tags: Atmosphere ; Carbon dioxide (CO2) ; Greenhouse gas (GHG)
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Measurement and simulation of the 16/17 April 2010 Eyjafjallajökull volcanic ash layer dispersion in the northern Alpine region
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Emeis S.; Forkel R.; Junkermann W.; et al. - Copernicus GmbH, 2011The spatial structure and the progression speed of the first ash layer from the Icelandic Eyjafjallajökull volcano which reached Germany on 16/17 April is investigated from remote sensing data and numerical simulations. The ceilometer network of the German Meteorological Service was able to follow the progression of the ash layer over the whole of Germany. This first ash layer turned out to be a rather shallow layer of only several hundreds of metres thickness which was oriented slantwise in the middle troposphere and which was brought downward by large-scale sinking motion over Southern Germa ...
[article]Measurement and simulation of the 16/17 April 2010 Eyjafjallajökull volcanic ash layer dispersion in the northern Alpine region
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Available online: http://dx.doi.org/10.5194/acp-11-2689-2011
S. Emeis ; R. Forkel ; W. Junkermann ; K. Schäfer ; H. Flentje ; S. Gilge ; W. Fricke ; M. Wiegner ; V. Freudenthaler ; S. Groβ ; L. Ries ; F. Meinhardt ; W. Birmili ; C. Münkel ; F. Obleitner ; P. Suppan
in Atmospheric Chemistry and Physics (ACP) > Vol. 11. N° 3 [03/01/2011] . - p.2689-2701The spatial structure and the progression speed of the first ash layer from the Icelandic Eyjafjallajökull volcano which reached Germany on 16/17 April is investigated from remote sensing data and numerical simulations. The ceilometer network of the German Meteorological Service was able to follow the progression of the ash layer over the whole of Germany. This first ash layer turned out to be a rather shallow layer of only several hundreds of metres thickness which was oriented slantwise in the middle troposphere and which was brought downward by large-scale sinking motion over Southern Germany and the Alps. Special Raman lidar measurements, trajectory analyses and in-situ observations from mountain observatories helped to confirm the volcanic origin of the detected aerosol layer. Ultralight aircraft measurements permitted the detection of the arrival of a second major flush of volcanic material in Southern Germany. Numerical simulations with the Eulerian meso-scale model MCCM were able to reproduce the temporal and spatial structure of the ash layer. Comparisons of the model results with the ceilometer network data on 17 April and with the ultralight aircraft data on 19 April were satisfying. This is the first example of a model validation study from this ceilometer network data.
Language(s): English
Format: Digital (Free)Tags: Alps, the ; Region VI - Europe ; Atmosphere ; Airborne ash ; Volcanic Eruption ; Natural hazards
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Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Bon D.M.; Ulbrich I.M.; de Gouw J.A.; et al. - Copernicus GmbH, 2011Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements an ...
[article]Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution
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Available online: http://dx.doi.org/10.5194/acp-11-2399-2011
D.M. Bon ; I.M. Ulbrich ; J.A. de Gouw ; C. Warneke ; W.C. Kuster ; M.L. Alexander ; A. Baker ; A.J. Beyersdorf ; D. Blake ; R. Fall ; J.L. Jimenez ; S.C. Herndon ; L.G. Huey ; W.B. Knighton ; J. Ortega ; S. Springston ; O. Vargas
in Atmospheric Chemistry and Physics (ACP) > Vol. 11. N° 3 [03/01/2011] . - p.2399-2421Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements and to aid in the identification of unknown VOCs. The VOC measurements are also compared to simultaneous canister samples and to two independent proton-transfer-reaction mass spectrometers (PTR-MS) deployed on a mobile and an airborne platform during MILAGRO. VOC diurnal cycles demonstrate the large influence of vehicle traffic and liquid propane gas (LPG) emissions during the night and photochemical processing during the afternoon. Emission ratios for VOCs and OVOCs relative to CO are derived from early-morning measurements. Average emission ratios for non-oxygenated species relative to CO are on average a factor of ~2 higher than measured for US cities. Emission ratios for OVOCs are estimated and compared to literature values the northeastern US and to tunnel studies in California. Positive matrix factorization analysis (PMF) is used to provide insight into VOC sources and processing. Three PMF factors were distinguished by the analysis including the emissions from vehicles, the use of liquid propane gas and the production of secondary VOCs + long-lived species. Emission ratios to CO calculated from the results of PMF analysis are compared to emission ratios calculated directly from measurements. The total PIT-MS signal is summed to estimate the fraction of identified versus unidentified VOC species.
Language(s): English
Format: Digital (Free)Tags: Atmosphere ; Volatile Organic Compounds (VOCs) ; Measure ; Urban zone ; Observations ; Mexico
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Size and time-resolved roadside enrichment of atmospheric particulate pollutants
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Amato F.; Viana M.; Richard A.; et al. - Copernicus GmbH, 2011Size and time-resolved roadside enrichments of atmospheric particulate pollutants in PM10 were detected and quantified in a Mediterranean urban environment (Barcelona, Spain). Simultaneous data from one urban background (UB), one traffic (T) and one heavy traffic (HT) location were analysed, and roadside PM10 enrichments (RE) in a number of elements arising from vehicular emissions were calculated. Tracers of primary traffic emissions (EC, Fe, Ba, Cu, Sb, Cr, Sn) showed the largest REs (>70%). Other traffic tracers (Zr, Cd) showed lower but still consistent REs (25–40%), similar to those obtai ...
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Distribution and air-sea exchange of mercury (Hg) in the Yellow Sea
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Ci Z.J.; Zhang X.S.; Wang Z.W.; et al. - Copernicus GmbH, 2011The Yellow Sea, surrounded by East China and the Korea Peninsula, is a potentially important receptor for anthropogenic mercury (Hg) emissions from East Asia. However, there is little documentation about the distribution and cycle of Hg in this marine system. During the cruise covering the Yellow Sea in July 2010, gaseous elemental mercury (GEM or Hg(0)) in the atmosphere, total Hg (THg), reactive Hg (RHg) and dissolved gaseous mercury (DGM, largely Hg(0)) in the waters were measured aboard the R/V Kexue III. The mean (±SD) concentration of GEM over the entire cruise was 2.61 ± 0.50 ng m−3 (ra ...
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Evaluating a 3-D transport model of atmospheric CO2 using ground-based, aircraft, and space-borne data
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Feng L.; Palmer P.I.; Yang Y.; et al. - Copernicus GmbH, 2011We evaluate the GEOS-Chem atmospheric transport model (v8-02-01) of CO2 over 2003–2006, driven by GEOS-4 and GEOS-5 meteorology from the NASA Goddard Global Modeling and Assimilation Office, using surface, aircraft and space-borne concentration measurements of CO2. We use an established ensemble Kalman Filter to estimate a posteriori biospheric+biomass burning (BS + BB) and oceanic (OC) CO2 fluxes from 22 geographical regions, following the TransCom-3 protocol, using boundary layer CO2 data from a subset of GLOBALVIEW surface sites. Global annual net BS + BB + OC CO2 fluxes over 2004–2006 for ...
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Chemical composition and mixing-state of ice residuals sampled within mixed phase clouds
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Ebert M.; Worringen A.; Benker N.; et al. - Copernicus GmbH, 2011During an intensive campaign at the high alpine research station Jungfraujoch, Switzerland, in February/March 2006 ice particle residuals within mixed-phase clouds were sampled using the Ice-counterflow virtual impactor (Ice-CVI). Size, morphology, chemical composition, mineralogy and mixing state of the ice residual and the interstitial (i.e., non-activated) aerosol particles were analyzed by scanning and transmission electron microscopy. Ice nuclei (IN) were identified from the significant enrichment of particle groups in the ice residual (IR) samples relative to the interstitial aerosol. In ...
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Sources of carbonaceous aerosol in the Amazon basin
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Gilardoni S.; Vignati E.; Marmer E.; et al. - Copernicus GmbH, 2011The quantification of sources of carbonaceous aerosol is important to understand their atmospheric concentrations and regulating processes and to study possible effects on climate and air quality, in addition to develop mitigation strategies.
In the framework of the European Integrated Project on Aerosol Cloud Climate Interactions (EUCAARI) fine (Dp < 2.5 μm) and coarse (2.5 μm < Dp <10 μm) aerosol particles were sampled from February to June (wet season) and from August to September (dry season) 2008 in the central Amazon basin. The mass of fine particles averaged 2.4 μg m−3 duri ...
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Characteristics of CALIOP attenuated backscatter noise: implication for cloud/aerosol detection
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Wu D.L.; Chae J.H.; Lambert A.; et al. - Copernicus GmbH, 2011A research algorithm is developed for noise evaluation and feature detection of the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) Level 1 (L1) backscatter data with an emphasis on cloud/aerosol features in the upper troposphere and lower stratosphere (UT/LS). CALIOP measurement noise of the version v2.01 and v2.02 L1 backscatter data aggregated to (5 km) horizontal resolution is analyzed with two approaches in this study. One is to compare the observed and modeled molecular scatter profiles by scaling the modeled profile (with a fitted scaling factor α) to the observed clear-sky ba ...
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Dry deposition of reactive nitrogen to European ecosystems: a comparison of inferential models across the NitroEurope network
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Flechard C.R.; Nemitz E.; Smith R.I.; et al. - Copernicus GmbH, 2011Inferential models have long been used to determine pollutant dry deposition to ecosystems from measurements of air concentrations and as part of national and regional atmospheric chemistry and transport models, and yet models still suffer very large uncertainties. An inferential network of 55 sites throughout Europe for atmospheric reactive nitrogen (Nr) was established in 2007, providing ambient concentrations of gaseous NH3, NO2, HNO3 and HONO and aerosol NH4+ and NO3− as part of the NitroEurope Integrated Project.
Network results providing modelled inorganic Nr dry deposition ...
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Long-term analysis of carbon dioxide and methane column-averaged mole fractions retrieved from SCIAMACHY
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Schneising O.; Buchwitz M.; Reuter M.; et al. - Copernicus GmbH, 2011Carbon dioxide (CO2) and methane (CH4) are the two most important anthropogenic greenhouse gases contributing to global climate change. SCIAMACHY onboard ENVISAT (launch 2002) was the first and is now with TANSO onboard GOSAT (launch 2009) one of only two satellite instruments currently in space whose measurements are sensitive to CO2 and CH4 concentration changes in the lowest atmospheric layers where the variability due to sources and sinks is largest.
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Representation of tropical deep convection in atmospheric models – Part 1: Meteorology and comparison with satellite observations
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Russo M.R.; Marécal V.; Hoyle C.R.; et al. - Copernicus GmbH, 2011Fast convective transport in the tropics can efficiently redistribute water vapour and pollutants up to the upper troposphere. In this study we compare tropical convection characteristics for the year 2005 in a range of atmospheric models, including numerical weather prediction (NWP) models, chemistry transport models (CTMs), and chemistry-climate models (CCMs). The model runs have been performed within the framework of the SCOUT-O3 (Stratospheric-Climate Links with Emphasis on the Upper Troposphere and Lower Stratosphere) project. The characteristics of tropical convection, such as seasonal c ...
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Atmospheric emissions from vegetation fires in Portugal (1990–2008): estimates, uncertainty analysis, and sensitivity analysis
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Rosa I.M.D.; Pereira J.M.C.; Tarantola S. - Copernicus GmbH, 2011Atmospheric emissions from wildfires in Portugal were estimated yearly over the period 1990–2008 using Landsat-based burnt area maps and land cover maps, national forest inventory data, biometric models, and literature review data. Emissions were calculated as the product of area burnt, biomass loading per unit area, combustion factor, and emission factor, using land cover specific values for all variables. Uncertainty associated with each input variable was quantified with a probability density function or a standard deviation value. Uncertainty and sensitivity analysis of estimates were perf ...
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The effect of H2SO4 – amine clustering on chemical ionization mass spectrometry (CIMS) measurements of gas-phase sulfuric acid
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Kurtén T.; Petäjä T.; Smith J.; et al. - Copernicus GmbH, 2011The state-of-the art method for measuring atmospheric gas-phase sulfuric acid is chemical ionization mass spectrometry (CIMS) based on nitrate reagent ions. We have assessed the possible effect of the sulfuric acid molecules clustering with base molecules on CIMS measurements using computational chemistry. From the computational data, three conclusions can be drawn. First, a significant fraction of the gas-phase sulfuric acid molecules are very likely clustered with amines if the amine concentration is around or above a few ppt. Second, some fraction of these acid-amine clusters may not be cha ...
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Origin and radiative forcing of black carbon transported to the Himalayas and Tibetan Plateau
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Kopacz M.; Mauzerall D.L.; Wang J.; et al. - Copernicus GmbH, 2011The remote and high elevation regions of central Asia are influenced by black carbon (BC) emissions from a variety of locations. BC deposition contributes to melting of glaciers and questions exist, of both scientific and policy interest, as to the origin of the BC reaching the glaciers. We use the adjoint of the GEOS-Chem model to identify the location from which BC arriving at a variety of locations in the Himalayas and Tibetan Plateau originates. We then calculate its direct and snow-albedo radiative forcing. We analyze the seasonal variation in the origin of BC using an adjoint sensitivity ...
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Size dependence of volume and surface nucleation rates for homogeneous freezing of supercooled water droplets
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Kuhn T.; Earle M.E.; Khalizov A.F.; et al. - Copernicus GmbH, 2011The relative roles of volume and surface nucleation were investigated for the homogeneous freezing of pure water droplets. Experiments were carried out in a cryogenic laminar aerosol flow tube using supercooled water aerosols with maximum volume densities at radii between 1 and 3 μm. Temperature- and size-dependent values of volume- and surface-based homogeneous nucleation rates between 234.8 and 236.2 K were derived using a microphysical model and aerosol phase compositions and size distributions determined from infrared extinction measurements in the flow tube. The results show that the cont ...
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Comparison of ambient aerosol extinction coefficients obtained from in-situ, MAX-DOAS and LIDAR measurements at Cabauw
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Zieger P.; Weingartner E.; Henzing J.; et al. - Copernicus GmbH, 2011In the field, aerosol in-situ measurements are often performed under dry conditions (relative humidity RH<30–40%). Since ambient aerosol particles experience hygroscopic growth at enhanced RH, their microphysical and optical properties – especially the aerosol light scattering – are also strongly dependent on RH. The knowledge of this RH effect is of crucial importance for climate forcing calculations or for the comparison of remote sensing with in-situ measurements. Here, we will present results from a four-month campaign which took place in summer 2009 in Cabauw, The Netherlands. The aerosol ...
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Comparison of ambient aerosol extinction coefficients obtained from in-situ, MAX-DOAS and LIDAR measurements at Cabauw
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Zieger P.; Weingartner E.; Henzing J.; et al. - Copernicus GmbH, 2011In the field, aerosol in-situ measurements are often performed under dry conditions (relative humidity RH<30–40%). Since ambient aerosol particles experience hygroscopic growth at enhanced RH, their microphysical and optical properties – especially the aerosol light scattering – are also strongly dependent on RH. The knowledge of this RH effect is of crucial importance for climate forcing calculations or for the comparison of remote sensing with in-situ measurements. Here, we will present results from a four-month campaign which took place in summer 2009 in Cabauw, The Netherlands. The aerosol ...
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Origin and radiative forcing of black carbon transported to the Himalayas and Tibetan Plateau
Atmospheric Chemistry and Physics (ACP), Vol. 11. N° 3. Kopacz M.; Mauzerall D.L.; Wang J.; et al. - Copernicus GmbH, 2011The remote and high elevation regions of central Asia are influenced by black carbon (BC) emissions from a variety of locations. BC deposition contributes to melting of glaciers and questions exist, of both scientific and policy interest, as to the origin of the BC reaching the glaciers. We use the adjoint of the GEOS-Chem model to identify the location from which BC arriving at a variety of locations in the Himalayas and Tibetan Plateau originates. We then calculate its direct and snow-albedo radiative forcing. We analyze the seasonal variation in the origin of BC using an adjoint sensitivity ...
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Beyond ‘dangerous’ climate change: emission scenarios for a new world
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 369. N° 1934. Anderson Kevin; Bows Alice - The Royal Society, 2011The Copenhagen Accord reiterates the international community’s commitment to ‘hold the increase in global temperature below 2 degrees Celsius’. Yet its preferred focus on global emission peak dates and longer-term reduction targets, without recourse to cumulative emission budgets, belies seriously the scale and scope of mitigation necessary to meet such a commitment. Moreover, the pivotal importance of emissions from non-Annex 1 nations in shaping available space for Annex 1 emission pathways received, and continues to receive, little attention. Building on previous studies, this paper uses a ...
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Cumulative carbon emissions, emissions floors and short-term rates of warming: implications for policy
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 369. N° 1934. Bowerman Niel H.A.; Frame David J.; Huntingford Chris; et al. - The Royal Society, 2011A number of recent studies have found a strong link between peak human-induced global warming and cumulative carbon emissions from the start of the industrial revolution, while the link to emissions over shorter periods or in the years 2020 or 2050 is generally weaker. However, cumulative targets appear to conflict with the concept of a ‘floor’ in emissions caused by sectors such as food production. Here, we show that the introduction of emissions floors does not reduce the importance of cumulative emissions, but may make some warming targets unachievable. For pathways that give a most likely ...
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No.10 - November 2010
is an issue of iLEAPS Newsletter. iLEAPS, 2011The latest iLEAPS Newsletter No. 10 deals with "Terrestrial feedbacks and Earth system models".
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WMO Greenhouse Gas Bulletin (GHG Bulletin) - No.7: The State of Greenhouse Gases in the Atmosphere Based on Global Observations through 2010
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Greenhouse gas emissions trends and projections in Europe 2011 : tracking progress towards Kyoto and 2020 targets
EEA, 2011This report presents an overview of the progress achieved so far by the EU, its Member States and other EEA member countries towards their respective targets under the Kyoto Protocol and the EU burden-sharing agreement, as well as 2020 targets set at EU level. The assessment is based on greenhouse gas (GHG) emission data in Europe for the period 2008–2010, including recent EEA estimates of proxy 2010 GHG emissions.
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CAWCR technical report, 44. Composition of the atmosphere - abstracts of the fifth CAWCR Workshop 15 November - 17 November 2011, Melbourne, Australia
The aims of the meeting are to: 1) understand the role of atmospheric chemistry and composition in global atmospheric change as expressed in the Australasian region and internationally; and 2) to provide a forum for atmospheric composition researchers from different disciplines (in-situ observations, remote sensing observations, modelling) to share ideas, enhance collaboration and develop a coordinated regional approach to characterising atmospheric processes in Australasia.
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CAWCR technical report, 42. Global climate goals for temperature, concentrations, emissions and cumulative emissions
Raupach Mickael R.; Harman Ian N.; Canadell Josep G. - Centre for Australian Weather and Climate Research, 2011There are many different ways of quantifying the broad goal of "avoidance of dangerous human interference with the climate system", including targets for global temperature rise, radiative forcing, greenhouse gas (GHG) concentrations, GHG emissions in particular years, and cumulative GHG emissions ("carbon budgets"). The purpose of this report is to provide relationships between these different statements of a climate goal. Broadly, the approach is to start from target for global temperature increase above preindustrial temperatures (such as two degrees Celsius or any other target, to be met w ...
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Extending atmospheric CO2 and tracer capabilities in ACCESS
Corbin Katherine D.; Law Rachel M. - Centre for Australian Weather and Climate Research, 2011 (CAWCR Technical Report-No. 035)The Australian Community Climate and Earth System Simulator (ACCESS) is a coupled landocean-atmosphere model being developed for a wide variety of applications. One key area of research with ACCESS is the carbon cycle, in particular atmospheric carbon dioxide (CO2) and methane (CH4) concentrations resulting from prescribed surface fluxes. ACCESS derives its atmospheric model from the UK Met Office Unified model (UM), which included both a specific atmospheric CO2 tracer (used for climate-carbon feedback studies) as well as other generic atmospheric tracers, developed for stratospheric transpor ...
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Report of the individual review of the annual submission of Iceland submitted in 2011
UNFCCC, 2011This report covers the in-country review of the 2011 annual submission of Iceland, coordinated by the UNFCCC secretariat, in accordance with decision 22/CMP.1. The review took place from 22 to 28 August 2011 in Reykjavik, Iceland, and was conducted by the following team of nominated experts from the UNFCCC roster of experts: generalist – Mr. Riccardo De Lauretis (Italy); energy – Mr. Norbert Nziramasanga (Zimbabwe); industrial processes – Ms. Valentina Idrissova (Kazakhstan); agriculture – Mr. Etienne Mathias (France); land use, land-use change and forestry (LULUCF) – Mr. Sandro Federici (San ...
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Tsunami Strike! Pacific Edition
Tsunami Strike! Pacific Edition is a scenario-based learning experience for kids from middle school through high school (approximate ages 13-17). The scenario tells the story of four main characters at different locations in the Pacific basin who are each impacted by a major tsunami that originates in Alaska’s Aleutian Islands. Over the course of the story, learners not only view the unfolding events and how each of the characters responds, but also observe how warning scientists analyze and communicate the tsunami threat. Fourteen short lessons provide interactive instruction focused on the s ...
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Improving conditions - The Global Climate Observing System (GCOS): in Meteorological Technology International, May 2011
The World Meteorological Organization is working in developing countries to improve atmospheric observations for climate change research.
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Integrated Assessment of Black Carbon and Tropospheric Ozone
World Meteorological Organization (WMO) ; United Nations Environment Programme (UNEP) - WMO, 2011 (WMO-No. 1073)Scientific evidence and new analyses demonstrate that control of black carbon particles and tropospheric ozone through rapid implementation of proven emission reduction measures would have immediate and multiple benefits for human well-being.Black carbon exists as particles in the atmosphere and is a major component of soot, it has significant human health and climate impacts.
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CAS/JSC WGNE Report, 27. 27th session of the CAS/JSC Working Group on Numerical Experimentation (WGNE-27)
World Meteorological Organization (WMO) ; Intergovernmental Oceanographic Commission (IOC); World Climate Research Programme (WCRP) ; et al. - WMO, 2011
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CAS/JSC WGNE Report, 26. 26th session of the CAS/JSC Working Group on Numerical Experimentation (WGNE-26)
World Meteorological Organization (WMO) ; Jakob Christian; Intergovernmental Oceanographic Commission (IOC); et al. - WMO, 2011
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Blue carbon policy framework 2.0 : based on the discussion of the International Blue Carbon Policy Working Group
Development and implementation of blue carbon-based activities now requires strategic policy and incentive mechanisms to achieve coastal conservation, restoration and sustainable use, and provide disincentives to drain or damage coastal systems. A first effort to develop such a strategic program was set out in the first edition of the Blue Carbon Policy Framework. Based on additional information and current progress a revised Blue Carbon Policy Framework 2.0 has now been developed. It updates the previous version and adds a detailed coordinated program of policy objectives and activities. It o ...
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How urban societies can adapt to resource shortage and climate change
Satterthwaite D. - The Royal Society, 2011The increased pressures on the world’s natural resources and ecological systems in the past century, has been accompanied by rapid urban population growth. Urban centres themselves have ecological reputations since they drive unsustainable environmental change, rapidly increasing the use of fossil fuels and carbon dioxide emissions due to increasing per capita consumption levels. They also lead to high levels of resource use and waste generation, causing serious ecological consequences locally, regionally and globally, especially in terms of climate change. However, addressing the issue of urb ...
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Carbon Dioxide and Climate : perspectives on a Scientific Assessment
Many of the findings of the Charney Report on CO2 induced climate change (1979) are still valid, despite 30 additional years of climate research and observations. This paper considers the reasons why the report was so prescient, and assesses the progress achieved since its publication. We suggest that emphasis on the importance of physical understanding gained through the use of theory and simple models, both in isolation and as an aid in the interpretation of the results of General Circulation Models, provided much of the authors’ insight at the time. Increased emphasis on these aspects of re ...
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Atmospheric Composition Irreversible Climate Change and Mitigation Policy
World Meteorological Organization (WMO) ; Pierrehumbert Raymond T.; Matthews D.L.; et al. - WMO, 2011The Earth’s atmosphere is changing due to anthropogenic increases of a range of gases and aerosols that influence the planetary energy budget. Policy has long been challenged to ensure that instruments such as the Kyoto Protocol or carbon trading deal with the wide range of lifetimes of these radiative forcing agents. Recent research has sharpened scientific understanding of the differences between various metrics used to compare emissions of different gases; as a result, there has been an improved understanding of how climate system time scales interact with the time scales of the forcing age ...
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Greenhouse gas emission trends and projections in Europe 2011 - Tracking progress towards Kyoto and 2020 targets
EEA, 2011This report presents an overview of the progress achieved so far by the EU, its Member States and other EEA member countries towards their respective targets under the Kyoto Protocol and the EU burden-sharing agreement, as well as 2020 targets set at EU level. The assessment is based on greenhouse gas (GHG) emission data in Europe for the period 2008–2010, including recent EEA estimates of proxy 2010 GHG emissions.
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Kyoto City to Reduce Greenhouse Gases by 40% by Fiscal 2030
JFS, 2011Kyoto City passed a proposed ordinance to completely revise the Kyoto City Global Warming Countermeasure Ordinance on September 29, 2010, and promulgated the new ordinance on October 12. The city aims to reduce greenhouse gases (GHGs) by 40 percent compared to 1990 levels by fiscal 2030, and by 25 percent by fiscal 2020.
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GAW Report, 195. WMO/GAW Expert Workshop on Global Long-term Measurements of Nitrogen Oxides and Recommendations for GAW Nitrogen Oxides Network
World Meteorological Organization (WMO) ; Gilge S.; Plass-Duelmer C.; et al. - WMO, 2011 (WMO/TD-No. 1570)Nitrogen oxides are a component of a group of reactive gases required to be measured in the GAW Programme. The reactive gases group focuses on gases known to be intimately involved in various aspects of the chemistry of the troposphere and includes surface ozone (O3), carbon monoxide (CO), volatile organic compounds (VOCs), and sulphur dioxide (SO2), as well as oxidized nitrogen species. The sum of nitric oxide (NO) and nitrogen dioxide (NO2) has traditionally been called NOx. The sum of oxidized nitrogen species with an oxidation number >1, both organic and inorganic, is referred to as ...
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GAW Report, 194. 15th WMO/IAEA Meeting of Experts on Carbon Dioxyide, other Greenhouse Gases and Related Tracers Measurement Techniques
The 15th WMO/IAEA Meeting of Experts on Carbon Dioxide, Other Greenhouse Gases and Related Tracers Measurement Techniques took place from 7 to 10 September 2009 at the MaxPlanck-Institute for Biogeochemistry in Jena, Germany. The meeting reviewed current WMO data quality objectives, covering such topics as carbon dioxide and other greenhouse gases, stable isotopes, radiocarbon in greenhouse gas measurements, calibration, quality control, data management and archiving. The experts also discussed new and emerging technologies, including measurements of greenhouse gases with high-precision spectr ...
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№ 7, ноября 2010 г. - Бюллетень ВМО по Парниковым Газам: Содержание парниковых газов в атмосфере по данным глобальных наблюдений в 2010 г.
BMO, 2011
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京都市、温室効果ガスを2030年度までに1990年度比で40%削減へ
JFS, 2011Le 29 septembre 2010, la ville de Kyoto a adopté un arrêté amendant la totalité des arrêtés concernant les mesures de lutte contre le réchauffement climatique et l'a promu le 12 octobre. La ville a pour objectif une réduction des émissions de gaz à effet de serre de 25% par rapport à 1990 d'ici 2020 et de 40% par rapport à 1990 d'ici 2030
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